We seek to quantify the factors that enhance the persistence of organic matter accumulation in soils and sediments, while also exploring the stability and vulnerability of organic matter to climate change. This research theme has two main components.
1) The climate sensitivity of rock organic matter oxidation and role of microbes in remineralisation
Rock organic matter oxidation is a major source of CO2 in the geological carbon cycle. It is increasingly recognised that microbial communities are present in the shallow rock weathering zone, but how they breakdown rock organic matter, and whether microbial communities drive apparent temperature sensitivity of CO2 release, are large knowledge gaps. We are tackling this using a range of field and laboratory methods, combing geochemistry and geomicrobiology approaches.
2) The stability of organic matter in high latitude and permafrost landscapes
The permafrost carbon cycle feedback involves a major natural flux of greenhouse gases which are are projected to increase over the next 100 years. Key uncertainties involve the reactivity of organic matter present across vast northern landscapes.
We are quantifying the time-dependent stability of organic matter using river sediments to capture organic matter inputs from across landscapes, mixing heterogenous sources, ages and mineralisation states. The stability of OC in river sediments is also important to assess in its own right. Sources of OC include microbial biomass, plant debris, mineral associated organic carbon, and rock derived organic carbon. We have built a new Ramped Oxidation system at Oxford to investigate the mechanisms regulating the preservation of organic carbon in soils and sediments.